| Dates |
Season |
Cup |
Round |
Match |
Result |
| 04.03.1997 |
1996/97 |
UC |
1/4 Final |
FC Schalke 04 - Valencia |
2:0 (1:0) |
| 18.03.1997 |
1996/97 |
UC |
1/4 Final |
Valencia - FC Schalke 04 |
1:1 (1:1) |
| 18.09.2007 |
2007/08 |
CL |
Group stage |
FC Schalke 04 - Valencia |
0:1 (0:0) |
| 28.11.2007 |
2007/08 |
CL |
Group stage |
Valencia - FC Schalke 04 |
0:0 (0:0) |
| 15.02.2011 |
2010/11 |
CL |
1/8 Final |
Valencia - FC Schalke 04 |
1:1 (1:0) |
| 10.03.2011 |
2010/11 |
CL |
1/8 Final |
FC Schalke 04 - Valencia |
3:1 (1:1) |
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