| Dates |
Season |
Cup |
Round |
Match |
Result |
| 25.02.2009 |
2008/09 |
CL |
1/8 Final |
Villarreal CF - Panathinaikos |
1:1 (0:0) |
| 10.03.2009 |
2008/09 |
CL |
1/8 Final |
Panathinaikos - Villarreal CF |
1:2 (0:0) |
| 21.09.2023 |
2023/24 |
EL |
Group stage |
Panathinaikos - Villarreal CF |
2:0 (1:0) |
| 30.11.2023 |
2023/24 |
EL |
Group stage |
Villarreal CF - Panathinaikos |
3:2 (2:0) |
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